Note[]
Some compunds listed here may not exist. This is not an error as those are just used as examples for clarity.
Elements and Simple Compounds[]
Elements:[]
Elements can be detonated by its symbol in SBrackets "[ & ]" or alone.
Silver = Ag or [Ag]
Binary Compounds and Coordination Compounds[]
(n)L; and/or SBrackets detonate Ligands:
Water = O[H,H] = H2O = O[2L; H]
Ammonia = NH3 = N[3L; H]
[Co(NH3)6]+3 = Co+3[6L; NH3] (full charges at end; Oxidation States after respective atom)
Sulfur Hexaflouride = S[6L; F]
More than one type of Ligand:[]
Simple: use "/" to separate types:
[CuCl5NH3]3- = Cu+2[5L;Cl/3L;NH3]3-
Chains and Rings[]
Chains[]
(n)[X]h where X is a compound, radical, or element. (if there is no [X] the base is Carbon (C))
2[OH]H = Peroxide
16H = hexadecane
Chains are numbered so that the first branch has the lowest numbered base and in the order of lowest to highest first atomic number:
5H[2;F, 4;Cl] = 2-fluoro-4-chloro-pentane
Rings[]
(n)[X]R (naming same as Chains) [For Cyclic]
(n)[X]r [For Aromatic]
6R = Cyclohexane
6r = Benzene
Rings are number based on the time system (12:00 is straight up, 6 is straight down, etc.)
Even Numbered Rigns[]
They're named based on the first member before 12
Basic Numbering Scheme.
6R[2:Cl] = 2-Chlorobenzene
Odd Numbered Rings[]
These are named at the point and then clockwise
3R[1-Cl] = Triange of 3 carbons with a chloro- group on the top vertex
Sub-branches ; Bonding and Stereochemistry[]
Sub-branches[]
Sub-branches are named with :~: (stopped with a comma at the end to avoid confusion
6R[2/s/O:Cl:] = Ring of 6 carbons with 2nd carbon having a O-Cl group
Bonding (no Bonding characteristics: - single, = double, # triple, and /n/ for higher order}[]
HC
Orbitals: s,p,f,g,h i...
Bond types sigma - s, pi - p, phi - f, delta - d
[<Central Atom Hybridizations,Orbitals>/<Bond(s)>/<Ligand or Branch Hybridization,Orbitals>]
O[2L; sp3/s/1s, H] = H2O with Bonding characteristics
Stereochemistry[]
Double Bond Stereochemistry is Signified with /s and \s
[F/C=C\F] = trans-fluoroethene
Others are signified after the Compound with a t (trans), c (cis), or using the R,S system (substituted for r,s for no confusion)
Final Section: Repeating Units and Disconnections[]
Repeating Units[]
For Compounds with repeating Units, the unit is compounds of elements, radicals, and/or compounds separated by commas
C[F,H] = CF2H2 (trans)
C[F,F] = CF2H2 (cis)
Disconnections[]
Disconnections can be Ionic:...
[Ca+2.2F-] = CaF2; [Na+.Cl-] = NaCl
Or
Inter-Ligandic:
Co[2L;NC+.C-1N] (hypothetical)